Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Matheson, I.A.; Sidebotton, H.W.; Tedder, J.M.
Title:   The reaction of trichloromethyl radicals with hydrogen chloride and a new estimation of the rate of combination of trichloromethyl radicals
Journal:   Int. J. Chem. Kinet.
Volume:   6
Year:   1974
Reference type:   Journal article
Squib:   1974MAT/SID493

Reaction:   ·CCl3 + HClCHCl3 + ·Cl
Reaction order:   2
Temperature:   385 - 446 K
Rate expression:   7.95x10-13 [cm3/molecule s] e-46894 [±5155 J/mole]/RT
Uncertainty:   1.32000005
Bath gas:   Cyclohexane
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
385 3.46E-19
400 5.98E-19
425 1.37E-18
446 2.56E-18