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Accessibility information
Author(s):   Bell, T.N.; Perkins, K.A.; Perkins, P.G.
Title:   The chlorination of paraffin hydrocarbons. Calculation of the activation energies and A factors for reactions in the total chlorination of methane
Journal:   J. Phys. Chem.
Volume:   81
Page(s):   2610 - 2614
Year:   1977
Reference type:   Journal article
Squib:   1977BEL/PER2610-2614

Reaction:   ·CCl3 + HClCHCl3 + ·Cl
Reaction order:   2
Temperature:   305 - 405 K
Rate expression:   2.51x10-13 [cm3/molecule s] e-42903 [J/mole]/RT
Category:  Theory
Data type:   Bond energy-bond order (BEBO)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
305 1.13E-20
325 3.19E-20
350 9.92E-20
375 2.65E-19
400 6.26E-19
405 7.35E-19