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Accessibility information
Author(s):   Doughty, A.; Mackie, J.C.
Title:   Kinetics of pyrolysis of the isomeric butenenitriles and kinetic modeling
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   272 - 281
Year:   1992
Reference type:   Journal article
Squib:   1992DOU/MAC272-281

Reaction:   CH2=CHCH2CNC2H3 + CH2CN
Reaction order:   1
Temperature:   1200 - 1500 K
Pressure:  18.27 - 20.26 bar
Rate expression:   3.39x1015 [s-1] e-345882 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 2.98E0
1225 6.05E0
1250 1.19E1
1275 2.29E1
1300 4.29E1
1325 7.85E1
1350 1.40E2
1375 2.46E2
1400 4.22E2
1425 7.11E2
1450 1.18E3
1475 1.91E3
1500 3.06E3