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©NIST, 2013
Accessibility information
Author(s):   da Silva, G.
Title:   Mystery of 1-Vinylpropargyl Formation from Acetylene Addition to the Propargyl Radical: An Open-and-Shut Case
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   2086 - 2095
Year:   2017
Reference type:   Journal article
Squib:   2017DAS2086-2095

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2017DAS2086-2095   C2H2 + ·CH2C≡CHCyclopentadienyl  300 - 2000   0.44   -14.20   1.33E05      2
  2017DAS2086-2095   C2H2 + ·CH2C≡CH → HC≡CCH=CHCH2·  300 - 2000   1.46E-04   -10.30   1.07E05      2
  2017DAS2086-2095   HC≡CCH=CHCH2· → Cyclopentadienyl  300 - 2000   7.83E33   -24.40   3.32E05      1
  2017DAS2086-2095   HC≡CCH=CHCH2· → C2H2 + ·CH2C≡CH  300 - 2000   1.48E28   -16.10   3.47E05      1
  2017DAS2086-2095   CyclopentadienylC2H2 + ·CH2C≡CH  300 - 2000   3.21E39   -24.40   5.36E05      1

Search returned 5 records.