Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Carr, S.; Shallcross, D.E.; Canosa-Mas, C.; Wenger, J.C.; Sidebottom, H.W.; Treacy, J.J.; Wayne, R.P.
Title:   A kinetic and mechanistic study of the gas-phase reactions of OH radicals and Cl atoms with some halogenated acetones and their atmospheric implications
Journal:   Phys. Chem. Chem. Phys.
Volume:   5
Page(s):   3874 - 3883
Year:   2003
Reference type:   Journal article
Squib:   2003CAR/SHA3874-3883

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003CAR/SHA3874-3883   Acetone + ·OH → Products  298   2.20E-13           2.20E-13  2
  2003CAR/SHA3874-3883   CH3COCH2Cl + ·OH → Products  298   4.20E-13           4.20E-13  2
  2003CAR/SHA3874-3883   1,1-Dichloroacetone + ·OH → Products  298   3.80E-13           3.80E-13  2
  2003CAR/SHA3874-3883   CCl3COCH3 + ·OH → Products  298   1.50E-14           1.50E-14  2
  2003CAR/SHA3874-3883   CH3COCH2F + ·OH → Products  298   2.10E-13           2.10E-13  2
  2003CAR/SHA3874-3883   CH3COCF3 + ·OH → Products  298   6.90E-15           6.90E-15  2
  2003CAR/SHA3874-3883   Acetone + ·Cl → Products  298   2.20E-13           2.20E-13  2
  2003CAR/SHA3874-3883   Acetone + ·OH → Products  298   0.94           0.94  2
  Reference reaction:  CH2ClCH2Cl + ·OH → Products 2
  2003CAR/SHA3874-3883   CH3COCH2Cl + ·Cl → Products  298   2.00E-13           2.00E-13  2
  2003CAR/SHA3874-3883   CH3COCH2Cl + ·OH → Products  298   1.81           1.81  2
  Reference reaction:  CH2ClCH2Cl + ·OH → Products 2
  2003CAR/SHA3874-3883   1,1-Dichloroacetone + ·Cl → Products  298   1.70E-14           1.70E-14  2
  2003CAR/SHA3874-3883   1,1-Dichloroacetone + ·OH → Products  298   1.66           1.66  2
  Reference reaction:  CH2ClCH2Cl + ·OH → Products 2
  2003CAR/SHA3874-3883   CCl3COCH3 + ·Cl → Products  298   1.70E-15           1.70E-15  2
  2003CAR/SHA3874-3883   CCl3COCH3 + ·OH → Products  298   0.70           0.70  2
  Reference reaction:  CH3CN + ·OH → Products 2
  2003CAR/SHA3874-3883   CH3COCH2F + ·Cl → Products  298   8.20E-14           8.20E-14  2
  2003CAR/SHA3874-3883   CH3COCH2F + ·OH → Products  298   0.89           0.89  2
  Reference reaction:  CH2ClCH2Cl + ·OH → Products 2
  2003CAR/SHA3874-3883   CH3COCF3 + ·Cl → Products  298   8.00E-16           8.00E-16  2
  2003CAR/SHA3874-3883   CH3COCF3 + ·OH → Products  298   0.32           0.32  2
  Reference reaction:  CH3CN + ·OH → Products 2
  2003CAR/SHA3874-3883   Acetone + ·Cl → Products  298   4.42           4.42  2
  Reference reaction:  CH3Cl + ·Cl → Products 2
  2003CAR/SHA3874-3883   CH3COCH2Cl + ·Cl → Products  298   0.91           0.91  2
  Reference reaction:  Acetone + ·Cl → Products 2
  2003CAR/SHA3874-3883   1,1-Dichloroacetone + ·Cl → Products  298   0.52           0.52  2
  Reference reaction:  CH2Cl2 + ·Cl → Products 2
  2003CAR/SHA3874-3883   CCl3COCH3 + ·Cl → Products  298   0.18           0.18  2
  Reference reaction:  CHCl3 + ·Cl → Products 2
  2003CAR/SHA3874-3883   CH3COCH2F + ·Cl → Products  298   0.64           0.64  2
  Reference reaction:  CH2ClCH2Cl + ·Cl → Products 2
  2003CAR/SHA3874-3883   CH3COCF3 + ·Cl → Products  298   0.08           0.08  2
  Reference reaction:  CHCl3 + ·Cl → Products 2

Search returned 24 records.