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Author(s):   Berces, T.; Trotman-Dickenson, A.F.
Title:   The reactions of methoxyl radicals with cyclopropane and isobutane
Journal:   J. Chem. Soc.
Year:   1961
Reference type:   Journal article
Squib:   1961BER/TRO348

Reaction:   iso-C4H10 + CH3CH3OH + tert-C4H9
Reaction order:   2
Temperature:   464 - 533 K
Pressure:  4.53E-3 - 7.60E-3 bar
Rate expression:   3.32x10-13 [cm3/molecule s] e-17128 [±8314472 J/mole]/RT
Uncertainty:   1.74000001
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
464 3.92E-15
475 4.34E-15
500 5.39E-15
525 6.56E-15
533 6.96E-15