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Title: Kinetics and mechanism of the pyrolysis of 1,3-cyclohexadiene. A thermal source of cyclohexadienyl radicals and hydrogen atoms. The addition of hydrogen atoms to benzene and toluene
Journal: J. Am. Chem. Soc.
Volume: 89
Page(s):
Year: 1967
Reference type: Journal article
Squib: 1967BEN/SHA5351
Reaction:
1,3-Cyclohexadiene + H· → H2 + Cyclohexadienyl
Reaction order:
2
Reference reaction:
Benzene + H· → CH2=CHCH=CHCH=CH·
Reference reaction order:
2
Temperature:
664
K
Pressure: 1.33E-2 - 0.12 bar
Rate expression:
3.0
Bath gas:
1,3-Cyclohexadiene
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.