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Title: Direct measurements of the peroxy-hydroperoxy radical isomerisation, a key step in hydrocarbon combustion
Journal: Chem. Phys. Lett.
Volume: 191
Page(s): 581 - 586
Year: 1992
Reference type: Journal article
Squib: 1992HUG/LIG581-586
Reaction:
(CH3)3CCH2OO → Neopentyl + O2
Reaction order:
1
Temperature:
700
K
Pressure: 0.73 bar
Rate expression:
9.1x103 [±6.4x102 s-1]
Bath gas:
He
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Laser induced fluorescence
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