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Author(s):   Hughes, K.J.; Lightfoot, P.D.; Pilling, M.J.
Title:   Direct measurements of the peroxy-hydroperoxy radical isomerisation, a key step in hydrocarbon combustion
Journal:   Chem. Phys. Lett.
Volume:   191
Page(s):   581 - 586
Year:   1992
Reference type:   Journal article
Squib:   1992HUG/LIG581-586

Reaction:   (CH3)3CCH2OO → Neopentyl + O2
Reaction order:   1
Temperature:   700 K
Pressure:  0.73 bar
Rate expression:   9.1x103 [±6.4x102 s-1]
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

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