 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Thermal decomposition of 1-butyne in shock waves
Journal: Int. J. Chem. Kinet.
Volume: 27
Page(s): 321 - 330
Year: 1995
Reference type: Journal article
Squib: 1995HID/HIG321-330
Reaction:
1-butyne → 1,2-butadiene
Reaction order:
1
Temperature:
1100 - 1600
K
Pressure: 1.25 - 2.33 bar
Rate expression:
2.5x1013 [s-1] e-271883 [J/mole]/RT
Bath gas:
Ar
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1100 | 3.07E0 |
| 1150 | 1.12E1 |
| 1200 | 3.66E1 |
| 1250 | 1.09E2 |
| 1300 | 2.98E2 |
| 1350 | 7.56E2 |
| 1400 | 1.79E3 |
| 1450 | 4.02E3 |
| 1500 | 8.52E3 |
| 1550 | 1.72E4 |
| 1600 | 3.33E4 |