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Author(s):   Cedeno, D.L.; Weitz, E.
Title:   Reactions of Fe(CO)3 and Fe(CO)4 with C2Cl4 in the Gas Phase Monitored by Transient Infrared Spectroscopy: Formation of Fe(CO)4(C2Cl4), Fe(CO)3(C2Cl4)2 and Novel Chloride Complexes Resulting from the Oxidative Addition of C2Cl4
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   8011 - 8026
Year:   2000
Reference type:   Journal article
Squib:   2000CED/WEI8011-8026

Reaction:   C2Cl4 + Fe(CO)4 → Fe(CO)4(C2Cl4)
Reaction order:   2
Temperature:   277 - 310 K
Pressure:  5.33E-2 - 9.33E-2 bar
Rate expression:   1.2x10-13 [±3.0x10-14 cm3/molecule s]
Bath gas:   CO
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   308 nm phhotolysis of Fe(CO)5 forming Fe(CO)3. Detected CO bands using tunable diode laser. Authors mention some uncertainty in identity and structure of some products. Total pressures of 40-70 torr CO with He added to make minimum pressure of 40 torr.

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