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Author(s):   Kistiakowsky, G.B.; Stauffer, C.H.
Title:   The kinetics of gaseous addition of halogen acids to isobutene
Journal:   J. Am. Chem. Soc.
Volume:   59
Page(s):   165 - 169
Year:   1937
Reference type:   Journal article
Squib:   1937KIS/STA165-169

Reaction:   Isobutene + HCltert-C4H9Cl
Reaction order:   2
Temperature:   543 - 645 K
Rate expression:   1.66x10-13 [cm3/molecule s] e-120560 [±9645 J/mole]/RT
Uncertainty:   10.0
Bath gas:   tert-C4H9Cl
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
543 4.20E-25
550 5.90E-25
575 1.86E-24
600 5.31E-24
625 1.40E-23
645 2.86E-23