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Author(s):   Aranda, A.; de Mera, Y.D.; Rodriguez, A.; Morales, L.; Martinez, E.
Title:   Kinetic study of the gas-phase reactions of Cl radicals with 3-pentanone and 3-hexanone
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   7027 - 7031
Year:   2004
Reference type:   Journal article
Squib:   2004ARA/DEM7027-7031

Reaction:   n-C3H7COC2H5 + ·Cl → Products
Reaction order:   2
Temperature:   263 - 333 K
Pressure:  1.33E-3 bar
Rate expression:   1.6x10-9 [±4.0x10-10 cm3/molecule s] e-7350 [±574 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   Error limits are 2 sigma.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
263 5.55E-11
275 6.43E-11
300 8.40E-11
325 1.05E-10
333 1.13E-10