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Author(s):   Thevenet, R.; Mellouki, A.; Le Bras, G.
Title:   Kinetics of OH and Cl Reactions with a Series of Aldehydes
Journal:   Int J. Chem. Kinet.
Volume:   32
Page(s):   676 - 685
Year:   2000
Reference type:   Journal article
Squib:   2000THE/MEL676-685

Reaction:   CH2=CHCHO + ·Cl → Products
Reaction order:   2
Reference reaction:   1-C6H14 + ·Cl → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.1x10-10 [cm3/molecule s]
Bath gas:   Air
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography
Comments:   Authors report the average rate constant derived from the experiments with different reference compounds (ethane, propane, n-butane, n-hexane): k(298)= (2.2?.3)E-10 cm^3/molecule s. The temperature is (298 ?3) K. Reactor is a 100 L Teflon bag with the Cl2 photolysis as a Cl source and a GC-FID detection of aldehydes.The rate constant for the reference reaction was taken from Atkinson, R. J. Phys. Chem. Ref. Data 1997, 26, 215

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