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Author(s):   Canosa-Mas, C.E.; Cotter, E.S.N.; Duffy, J.; Thompson, K.C.; Wayne, R.P.
Title:   The Reactions of Atomic Chlorine with Acrolein, Methacrolein and Methyl Vinyl Ketone
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   3075 - 3084
Year:   2001
Reference type:   Journal article
Squib:   2001CAN/COT3075-3084

Reaction:   CH2=CHCHO + ·Cl → Products
Reaction order:   2
Temperature:   299 K
Pressure:  2.13E-3 bar
Rate expression:   1.1x10-10 [±2.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
Comments:   Reported uncertainties are at 95% confidence limit.

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