Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Canosa-Mas, C.E.; Cotter, E.S.N.; Duffy, J.; Thompson, K.C.; Wayne, R.P.
Title:   The Reactions of Atomic Chlorine with Acrolein, Methacrolein and Methyl Vinyl Ketone
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   3075 - 3084
Year:   2001
Reference type:   Journal article
Squib:   2001CAN/COT3075-3084

Reaction:   CH2=CHCHO + ·Cl → Products
Reaction order:   2
Reference reaction:   C3H8 + ·Cl → Products
Reference reaction order:   2
Temperature:   299 K
Pressure:  1.01 bar
Rate expression:   2.2x10-10±3.0x10-11
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Reported uncertainties are at 95% confidence limit and include uncertainty in reference rate constant. Reference rate constant is (1.37 +- 0.11)e-10 cm3 molecule-1 s-1.

View full bibliographic record.