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Author(s):   Aranda, A.; Diaz de Mera, Y.; Rodriguez, A.; Rodriguez, D.; Martinez, E.
Title:   A Kinetic and Mechanistic Study of the Reaction of Cl Atoms with Acrolein: Temperature Dependence for Abstraction Channel
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   5717 - 5721
Year:   2003
Reference type:   Journal article
Squib:   2003ARA/DIA5717-5721

Reaction:   CH2=CHCHO + ·Cl → Products
Reaction order:   2
Temperature:   260 - 333 K
Pressure:  6.67E-4 - 4.00E-3 bar
Rate expression:   9.3x10-11 [±9.7x10-11 cm3/molecule s] e-1239 [±2469 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
260 5.24E-11
275 5.41E-11
300 5.66E-11
325 5.88E-11
333 5.95E-11