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Title: Product Branching Fractions of the CH plus Propene Reaction from Synchrotron Photoionization Mass Spectrometry
Journal: J. Phys. Chem. A
Volume: 117
Page(s): 6450 - 6457
Year: 2013
Reference type: Journal article
Squib: 2013TRE/PRE6450-6457
Reaction:
CH3CH=CH2 + CD → 1,2-butadiene + D
Reaction order:
2
Reference reaction:
CH3CH=CH2 + CD → C4H6 + D
Reference reaction order:
2
Temperature:
298
K
Pressure: 5.33E-3 bar
Rate expression:
9.7x10-1±2.0x10-1
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Mass spectrometry
Comments:
The overall uncertainty is estimated at 20%.
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