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Author(s):   Chen, W.-Y.; Matsui, H.; Wang, N.-S.
Title:   A comparative study on the production yield of H atom in the thermal decomposition of i-C4H10 and n-C4H10: Examination of the contribution of the roaming radical channels
Journal:   Chem. Phys. Lett.
Volume:   691
Page(s):   56 - 60
Year:   2018
Reference type:   Journal article
Squib:   2018CHE/MAT56-60

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2018CHE/MAT56-60   iso-C4H102-C3H7 + ·CH3  1490 - 1800   2.15E16       3.48E05      1
  2018CHE/MAT56-60   1-C4H101-C3H7 + ·CH3  1470 - 1800   6.72E12       2.55E05      1
  2018CHE/MAT56-60   1-C4H10·C2H5 + ·C2H5  1470 - 1800   9.28E12       2.55E05      1
    2018CHE/MAT56-60   1-C4H10·C2H5 + ·C2H5  1470 - 1800                  1
  Reference reaction:  1-C4H10 → Products 1
    2018CHE/MAT56-60   iso-C4H102-C3H7 + ·CH3  1470 - 1800                  1
  Reference reaction:  iso-C4H10 → Products 1
  2018CHE/MAT56-60   iso-C4H10CH4 + CH3CH=CH2  1470 - 1800   <0.12              1
  Reference reaction:  iso-C4H10 → Products 1
  2018CHE/MAT56-60   1-C4H10CH4 + CH3CH=CH2  1470 - 1800   <0.05              1
  Reference reaction:  1-C4H10 → Products 1

Search returned 7 records.