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Author(s):   Sanders, W.A.; Lin, M.C.
Title:   Kinetics and mechanism of reactions of NF2 with olefins. Reinterpretation of existing data and estimation of C-N bond energies of alkyldifluoroamines
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   83
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987SAN/LIN905

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987SAN/LIN905   C2H4 + NF2 → F2NCH2CH2  330 - 430   2.34E-14       6.19E04      2
  1987SAN/LIN905   C2H4 + NF2 → F2NCH2CH2  330 - 430   1.12E-32       6.24E04      3
  1987SAN/LIN905   CH2=CHCl + NF2 → CH2CH(NF2)Cl  330 - 430   4.68E-15       5.44E04      2
  1987SAN/LIN905   CH2=CHCl + NF2 → CH2CH(NF2)Cl  330 - 430   6.04E-33       5.52E04      3
  1987SAN/LIN905   1-C4H8 + NF2 → C2H5CHCH2NF2  330 - 430   3.47E-14       5.85E04      2
  1987SAN/LIN905   1-C4H8 + NF2 → C2H5CHCH2NF2  330 - 440   3.17E-34       4.18E04      3
  1987SAN/LIN905   CH3CH=CH2 + NF2 → CH3CHCH2NF2  330 - 430   8.92E-14       6.11E04      2
  1987SAN/LIN905   CH3CH=CH2 + NF2 → CH3CHCH2NF2  330 - 430   2.95E-33       5.02E04      3
  1987SAN/LIN905   Isobutene + NF2 → (CH3)2CCH2NF2  330 - 430   9.55E-15       4.98E04      2
  1987SAN/LIN905   Isobutene + NF2 → (CH3)2CCH2NF2  330 - 430   3.03E-32       5.06E04      3
  1987SAN/LIN905   Cyclopentene + NF2 → Cyclopentyl, 2-(difluoroamino)-  330 - 430   1.07E-15       4.61E04      2
  1987SAN/LIN905   Cyclopentene + NF2 → Cyclopentyl, 2-(difluoroamino)-  330 - 430   2.14E-32       5.31E04      3
  1987SAN/LIN905   (CH3)2C=CHCH3 + NF2 → CH3CH(NF2)C(CH3)2  330 - 430   2.66E-15       4.35E04      2
  1987SAN/LIN905   (CH3)2C=CHCH3 + NF2 → CH3CH(NF2)C(CH3)2  330 - 430   2.57E-33       4.18E04      3
  1987SAN/LIN905   (CH3)2C=C(CH3)2 + NF2 → (CH3)2C(NF2)C(CH3)2  330 - 430   2.82E-16       3.31E04      2
  1987SAN/LIN905   (CH3)2C=C(CH3)2 + NF2 → (CH3)2C(NF2)C(CH3)2  330 - 430   2.76E-33       3.97E04      3
  1987SAN/LIN905   (Z)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   1.32E-14       5.23E04      2
  1987SAN/LIN905   (Z)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   7.78E-33       5.11E04      3
  1987SAN/LIN905   CH2=CHBr + NF2 → CH2CH(NF2)Br  330 - 430   1.99E-14       5.85E04      2
  1987SAN/LIN905   CH2=CHBr + NF2 → CH2CH(NF2)Br  330 - 430   5.02E-33       5.52E04      3
  1987SAN/LIN905   (E)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   8.32E-15       5.11E04      2
  1987SAN/LIN905   (E)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  330 - 430   3.31E-32       5.31E04      3
  1987SAN/LIN905   CH3CHCH2NF2CH3CH=CH2 + NF2  330 - 430   2.45E13       5.99E04      1
  1987SAN/LIN905   CH3CHCH2NF2CH3CH=CH2 + NF2  330 - 430   8.14E-07       4.94E04      2
  1987SAN/LIN905   F2NCH2CH2C2H4 + NF2  330 - 430   3.55E12       5.73E04      1
  1987SAN/LIN905   F2NCH2CH2C2H4 + NF2  330 - 430   1.20E-06       5.65E04      2
  1987SAN/LIN905   C2H5CHCH2NF21-C4H8 + NF2  330 - 430   4.79E11       4.86E04      1
  1987SAN/LIN905   C2H5CHCH2NF21-C4H8 + NF2  330 - 430   4.47E-09       3.18E04      2
  1987SAN/LIN905   CH3CH(NF2)CHCH3(Z)-2-C4H8 + NF2  330 - 430   7.41E13       5.94E04      1
  1987SAN/LIN905   CH3CH(NF2)CHCH3(Z)-2-C4H8 + NF2  330 - 430   4.37E-05       5.77E04      2
  1987SAN/LIN905   CH3CH(NF2)CHCH3(E)-2-C4H8 + NF2  330 - 430   3.72E13       5.82E04      1
  1987SAN/LIN905   CH3CH(NF2)CHCH3(E)-2-C4H8 + NF2  330 - 430   1.48E-04       6.03E04      2
  1987SAN/LIN905   (CH3)2CCH2NF2Isobutene + NF2  330 - 430   3.39E09       3.01E04      1
  1987SAN/LIN905   (CH3)2CCH2NF2Isobutene + NF2  330 - 430   1.07E-08       3.13E04      2
  1987SAN/LIN905   CH3CH(NF2)C(CH3)2 → (CH3)2C=CHCH3 + NF2  330 - 430   5.25E11       4.06E04      1
  1987SAN/LIN905   CH3CH(NF2)C(CH3)2 → (CH3)2C=CHCH3 + NF2  330 - 430   4.90E-07       3.89E04      2
  1987SAN/LIN905   (CH3)2C(NF2)C(CH3)2 → (CH3)2C=C(CH3)2 + NF2  330 - 430   8.91E10       3.05E04      1
  1987SAN/LIN905   (CH3)2C(NF2)C(CH3)2 → (CH3)2C=C(CH3)2 + NF2  330 - 430   8.72E-07       3.68E04      2
  1987SAN/LIN905   Cyclopentyl, 2-(difluoroamino)- → Cyclopentene + NF2  330 - 430   7.24E10       4.18E04      1
  1987SAN/LIN905   Cyclopentyl, 2-(difluoroamino)- → Cyclopentene + NF2  330 - 430   1.45E-06       4.86E04      2
  1987SAN/LIN905   CH2CH(NF2)Cl → CH2=CHCl + NF2  330 - 430   3.72E10       3.97E04      1
  1987SAN/LIN905   CH2CH(NF2)Cl → CH2=CHCl + NF2  330 - 430   4.78E-08       4.06E04      2
  1987SAN/LIN905   CH2CH(NF2)Br → CH2=CHBr + NF2  330 - 430   2.09E12       5.11E04      1
  1987SAN/LIN905   CH2CH(NF2)Br → CH2=CHBr + NF2  330 - 430   5.25E-07       4.81E04      2

Search returned 44 records.