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Author(s):   Dunlea, E.J.; Talukdar, R.K.; Ravishankara, A.R.
Title:   Kinetic studies of the reactions of O2(b1Σg+) with several atmospheric molecules
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   3912 - 3920
Year:   2005
Reference type:   Journal article
Squib:   2005DUN/TAL3912-3920

Reaction:   O2(b1Sigma_g+) + CO → Products
Reaction order:   2
Temperature:   295 K
Pressure:  9.53E-2 bar
Rate expression:   3.74x10-15 [±8.7x10-16 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
Comments:   Singlet sigma oxygen produced directly by 762-nm photolysis and monitored by following O-atom production from the reaction with O3.

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