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Accessibility information
Author(s):   Hayman, G.D.; Jenkin, M.E.; Murrells, T.P.; Johnson, C.E.
Title:   Tropospheric degradation chemistry of HCFC-123 (CF3CHCl2): a proposed replacement chlorofluorocarbon
Journal:   Atmos. Environ.
Volume:   28
Page(s):   421 - 437
Year:   1994
Reference type:   Journal article
Squib:   1994HAY/JEN421-437

Reaction:   HO2 + CF3O2 → O2 + CF3OOH
Reaction order:   2
Temperature:   298 - 308 K
Pressure:  1.01 bar
Rate expression:   1.3x10-13 [cm3/molecule s] e6568 [J/mole]/RT
Bath gas:   N2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.84E-12
300 1.81E-12
308 1.69E-12