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Author(s):   Papadimitriou, V.C.; Kambanis, K.G.; Lazarou, Y.G.; Papagiannakopoulos, P.
Title:   Kinetic study for the reactions of several hydrofluoroethers with chlorine atoms
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   2666 - 2674
Year:   2004
Reference type:   Journal article
Squib:   2004PAP/KAM2666-2674

Reaction:   CF3CHFCF2OCH3 + ·Cl → Products
Reaction order:   2
Temperature:   273 - 363 K
Rate expression:   8.72x10-12 [±2.93x10-12 cm3/molecule s] e-9246 [±1546 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Very low pressure cells (VLPP,Knudsen)
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   Uncertainties in the Arrhenius parameters are 2 sigma.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 1.48E-13
275 1.53E-13
300 2.14E-13
325 2.85E-13
350 3.64E-13
363 4.07E-13