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Author(s):   Garcia de Sarmiento, M.A.; Dominguez, R.M.; Chuchani, G.
Title:   Electronic effects of polar substituents at the acyl carbon. The pyrolysis kinetics of several isopropyl esters
Journal:   J. Phys. Chem.
Volume:   84
Page(s):   2531 - 2535
Year:   1980
Reference type:   Journal article
Squib:   1980GAR/DOM2531-2535

Reaction:   ClCH2C(O)OCH(CH3)2CH2ClCOOH + CH3CH=CH2
Reaction order:   1
Temperature:   584 - 612 K
Pressure:  3.53E-2 - 0.33 bar
Rate expression:   1.1x1013 [s-1] e-183750 [±5512 J/mole]/RT
Uncertainty:   5.0
Bath gas:   ClCH2C(O)OCH(CH3)2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
584 4.04E-4
600 1.11E-3
612 2.28E-3