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Author(s):   Alwe, H. D.; Sharma, A.; Walavalkar, M. P.; Dhanya, S.; Naik, P. D.
Title:   Reactivity of Cl Atom with Triple-Bonded Molecules. An Experimental and Theoretical Study with Alcohols
Journal:   J. Phys. Chem. A
Volume:   118
Page(s):   7695 - 7706
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014ALW/SHA7695-7706

Reaction:   HC≡CCH2CH2OH + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.07 bar
Rate expression:   4.3x10-10 [±1.3x10-10 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Average of determinations using cis-butene, 1-butene, butane, and propargyl alcohol as reference compounds. The nature of the reported uncertainty is unclear.

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