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Title: The reactions of alkyl radicals. Part 1.-n-Propyl radicals from the photolysis of n-butyraldehyde
Journal: Trans. Faraday Soc.
Volume: 55
Page(s):
Year: 1959
Reference type: Journal article
Squib: 1959KER/TRO572
Reaction:
CH3CH2CH2CHO + 1-C3H7 → C3H8 + CH3CH2CH2CO
Reaction order:
2
Reference reaction:
1-C3H7 + 1-C3H7 → 1-C6H14
Temperature:
464 - 573
K
Pressure: 1.20E-2 - 4.40E-2 bar
Rate expression:
3.32x10-13 [cm3/molecule s] e-45148 [J/mole]/RT
Bath gas:
CH3CH2CH2CHO
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 464 | 2.75E-18 |
| 475 | 3.60E-18 |
| 500 | 6.38E-18 |
| 525 | 1.07E-17 |
| 550 | 1.71E-17 |
| 573 | 2.55E-17 |