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Accessibility information
Author(s):   Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   The reactions of alkyl radicals. Part 1.-n-Propyl radicals from the photolysis of n-butyraldehyde
Journal:   Trans. Faraday Soc.
Volume:   55
Year:   1959
Reference type:   Journal article
Squib:   1959KER/TRO572

Reaction:   CH3CH2CH2CHO + 1-C3H7C3H8 + CH3CH2CH2CO
Reaction order:   2
Reference reaction:   1-C3H7 + 1-C3H71-C6H14
Temperature:   464 - 573 K
Pressure:  1.20E-2 - 4.40E-2 bar
Rate expression:   3.32x10-13 [cm3/molecule s] e-45148 [J/mole]/RT
Bath gas:   CH3CH2CH2CHO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
464 2.75E-18
475 3.60E-18
500 6.38E-18
525 1.07E-17
550 1.71E-17
573 2.55E-17