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Accessibility information
Author(s):   Forgeteg, S.; Berces, T.; Dobe, S.
Title:   The kinetics and mechanism of n-butyraldehyde photolysis in the vapor phase at 313 nm
Journal:   Int. J. Chem. Kinet.
Volume:   11
Year:   1979
Reference type:   Journal article
Squib:   1979FOR/BER219

Reaction:   CH3CH2CH2CHO + 1-C3H7C3H8 + CH3CH2CH2CO
Reaction order:   2
Temperature:   273 - 529 K
Pressure:  0.13 bar
Rate expression:   1.66x10-13 [cm3/molecule s] e-27604 [±2212 J/mole]/RT
Uncertainty:   2.0
Bath gas:   CH3CH2CH2CHO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 8.68E-19
275 9.49E-19
300 2.59E-18
325 6.08E-18
350 1.26E-17
375 2.37E-17
400 4.13E-17
425 6.72E-17
450 1.04E-16
475 1.53E-16
500 2.17E-16
525 2.98E-16
529 3.12E-16