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Author(s):   Atkinson, R.; Baulch, D.L.; Cox, R.A.; Hampson, R.F., Jr.; Kerr, J.A.; Rossi, M.J.; Troe, J.
Title:   Evaluated kinetic, photochemical and heterogeneous data for atmospheric chemistry: supplement V, IUPAC subcommittee on gas kinetic data evaluation for atmospheric chemistry
Journal:   J. Phys. Chem. Ref. Data
Volume:   26
Page(s):   521 - 1011
Year:   1997
Reference type:   Journal article
Squib:   1997ATK/BAU521-1011

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997ATK/BAU521-1011   O(1D) + CCl4 → Products  298   3.30E-10           3.30E-10  2
  1997ATK/BAU521-1011   O(1D) + CH3CHF2 → Products  298   2.01E-10           2.01E-10  2
  1997ATK/BAU521-1011   CH3CHClO2· + CH3CHClO2· → Products  298   5.00E-12           5.00E-12  2
  1997ATK/BAU521-1011   O(1D) + CHFCl2 → Products  175 - 340   1.91E-10           1.91E-10  2
  1997ATK/BAU521-1011   O(1D) + COCl2 → Products  298   3.60E-10           3.60E-10  2
  1997ATK/BAU521-1011   O(1D) + CF3CH2Cl → Products  298   1.20E-10           1.20E-10  2
  1997ATK/BAU521-1011   O(1D) + CF2Cl2 → Products  298   1.40E-10           1.40E-10  2
  1997ATK/BAU521-1011   O(1D) + CF3CHCl2 → Products  298   2.01E-10           2.01E-10  2
  1997ATK/BAU521-1011   O(1D) + COF2CO2 + F2  298   2.19E-11           2.19E-11  2
  1997ATK/BAU521-1011   O(1D) + COF2COF2 +   298   5.20E-11           5.20E-11  2
  1997ATK/BAU521-1011   O(1D) + C2F5H → Products  298   1.20E-10           1.20E-10  2
  1997ATK/BAU521-1011   O(1D) + CH3F → Products  298   1.60E-10           1.60E-10  2
  1997ATK/BAU521-1011   O(1D) + CF3CH2F → Products  298   4.90E-11           4.90E-11  2
  1997ATK/BAU521-1011   O(1D) + HF → Products  298   1.00E-10           1.00E-10  2
  1997ATK/BAU521-1011   O(1D) + CH3CCl2F → Products  298   2.61E-10           2.61E-10  2
  1997ATK/BAU521-1011   CH2FCHFO2· + NO → CH2FCHFO· + NO2  298   >9.00E-12           9.00E-12  2
  1997ATK/BAU521-1011   CH2O + HO2HOCH2OO  275 - 333   9.71E-15       -5197   7.91E-14  2
  1997ATK/BAU521-1011   CH2O + ·OHHCO + H2O  240 - 300   8.60E-12       -166   9.20E-12  2
  1997ATK/BAU521-1011   CH2O + Br·HCO + HBr  223 - 480   1.69E-11       6652   1.16E-12  2
  1997ATK/BAU521-1011   C2H2 + NO3 → Products  298   <1.00E-16           1.00E-16  2
  1997ATK/BAU521-1011   CH2O + NO3HCO + HNO3  298   5.80E-16           5.80E-16  2
  1997ATK/BAU521-1011   CH2O + ·ClHCO + HCl  200 - 500   8.20E-11       283   7.32E-11  2
  1997ATK/BAU521-1011   CCl4 + ·OH·CCl3 + HOCl  250 - 300   <1.00E-12       1.88E04   5.09E-16  2
  1997ATK/BAU521-1011   C2H5OH + ·OH → Other Products + H2O  270 - 340   4.10E-12       582   3.24E-12  2
  1997ATK/BAU521-1011   HCOOH + ·OH → Products  290 - 450   4.50E-13           4.50E-13  2
  1997ATK/BAU521-1011   HCOOH + ·Cl → Other Products + HCl  298   2.01E-13           2.01E-13  2
  1997ATK/BAU521-1011   CH3C(O)OH + ·OH → Products  298   8.00E-13           8.00E-13  2
  1997ATK/BAU521-1011   CH3C(O)OH + ·Cl → Other Products + HCl  298   2.81E-14           2.81E-14  2
  1997ATK/BAU521-1011   CH3OH + ·OH → Other Products + H2O  240 - 300   3.11E-12       2993   9.28E-13  2
  1997ATK/BAU521-1011   CH3OH + ·Cl(·)CH2OH + HCl  200 - 573   5.50E-11           5.50E-11  2
  1997ATK/BAU521-1011   iso-C3H7OH + ·OH → Products  270 - 340   2.71E-12       -1580   5.12E-12  2
  1997ATK/BAU521-1011   iso-C3H7OH + NO3 → Products  298   <5.00E-15           5.00E-15  2
  1997ATK/BAU521-1011   iso-C3H7OH + ·Cl → Other Products + HCl  298   8.40E-11           8.40E-11  2
  1997ATK/BAU521-1011   Acetone + ·OHCH3C(O)CH2(·) + H2O  240 - 300   2.81E-12       6319   2.19E-13  2
  1997ATK/BAU521-1011   Acetone + NO3CH3C(O)CH2(·) + HNO3  298   <3.01E-17           3.01E-17  2
  1997ATK/BAU521-1011   Acetone + ·ClCH3C(O)CH2(·) + HCl  298   3.50E-12           3.50E-12  2
  1997ATK/BAU521-1011   CHCl3 + ·OH·CCl3 + H2O  240 - 300   9.30E-13       5488   1.02E-13  2
  1997ATK/BAU521-1011   CHCl3 + ·Cl·CCl3 + HCl  240 - 330   4.90E-12       1.03E04   7.64E-14  2
  1997ATK/BAU521-1011   CH3CH2CH2OH + ·OH → Products  298   5.50E-12           5.50E-12  2
  1997ATK/BAU521-1011   CH3CH2CH2OH + ·Cl → Other Products + HCl  298   1.50E-10           1.50E-10  2
  1997ATK/BAU521-1011   CH3CCl3 + ·OHH2O + CCl3CH2  240 - 300   1.20E-12       1.20E04   9.57E-15  2
  1997ATK/BAU521-1011   CH3CCl3 + ·ClHCl + CCl3CH2  298   <4.00E-14           4.00E-14  2
  1997ATK/BAU521-1011   CH4 + ·OH·CH3 + H2O  240 - 300   2.31E-12       1.46E04   6.28E-15  2
  1997ATK/BAU521-1011   CH4 +