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Author(s):   Witter, M.; Berndt, T.; Boge, O.; Stratmann, F.; Heintzenberg, J.
Title:   Gas-Phase Ozonolysis: Rate Coefficients for a Series of Terpenes and Rate Coefficients and OH Yields for 2-Methyl-2-butene and 2,3-Dimethyl-2-butene
Journal:   Int J. Chem. Kinet.
Volume:   34
Page(s):   394 - 403
Year:   2002
Reference type:   Journal article
Squib:   2002WIT/BER394-403

Reaction:   (CH3)2C=CHCH3 + O3 → Products
Reaction order:   2
Temperature:   295 K
Pressure:  0.50 bar
Rate expression:   4.1x10-16 [±5.0x10-17 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Direct stopped flow measurement, no radical scavenger, second order (HC ~ O3), kinetic model used, OH radical yield found to be 0.47 +/- 0.04

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