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Author(s):   McDowell, D.R.; Holmes, B.E.
Title:   Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. Part III: reactions of CF3 + CF3CH2CHCF3 and CF3CH2CHCF3 + CF3CH2CHCF3
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   109 - 114
Year:   1996
Reference type:   Journal article
Squib:   1996MCD/HOL109-114

Reaction:   CF3CH2CH(·)CF3 + ·CF3 → Other Products + CHF3
Reaction order:   2
Reference reaction:   CF3CH2CH(·)CF3 + ·CF3 → Adduct
Reference reaction order:   2
Temperature:   298 K
Rate expression:   6.61x10-2±1.3x10-2
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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