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Accessibility information
Author(s):   Dombi, A.; Huhn, P.
Title:   Effects of olefins on the thermal decomposition of propane. I. The model reaction
Journal:   Magy. Kem. Foly.
Volume:   91
Page(s):   22 - 27
Year:   1985
Reference type:   Journal article
Squib:   1985DOM/HUH22-27

Reaction:   C3H8 + iso-C3H7C3H8 + 1-C3H7
Reaction order:   2
Reference reaction:   iso-C3H7CH3CH=CH2 +
Reference reaction order:   1
Temperature:   760 - 830 K
Pressure:  2.67E-3 - 2.53E-2 bar
Rate expression:   1.78x10-51 [cm3/molecule] e114740 [±4590 J/mole]/RT
Uncertainty:   2.20000005
Bath gas:   C3H8
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule]
760 1.37E-43
775 9.61E-44
800 5.51E-44
825 3.27E-44
830 2.95E-44