Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Oguchi, T.; Ishizaki, A.; Kakuta, Y.; Matsui, H.; Miyoshi, A.
Title:   Mechanism of the reactions of butenes with O(3P): The yields of CH3 and C2H5
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   1409 - 1416
Year:   2004
Reference type:   Journal article
Squib:   2004OGU/ISH1409-1416

Reaction:   (E)-2-C4H8 + ·C2H5 + CH3CO
Reaction order:   2
Reference reaction:   (E)-2-C4H8 + → Other Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  6.67E-3 bar
Rate expression:   2.9x10-1±5.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   Photoionization mass spectrometry utilized. O-atoms generated by the ArF photolysis of SO2.

Signal intensity of C2H5 calibrated by comparison with yield from Cl + C2H6.

View full bibliographic record.