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Title: The reactions of bromine atoms with alkanes and methyl halides
Journal: J. Chem. Soc. A
Page(s):
Year: 1960
Reference type: Journal article
Squib: 1960FET/KNO4177
Reaction:
iso-C4H10 + Br· → tert-C4H9 + HBr
Reaction order:
2
Reference reaction:
1-C4H10 + Br· → sec-C4H9 + HBr
Reference reaction order:
2
Temperature:
262 - 371
K
Rate expression:
1.32x10-1±9.2x10-3 e11391 [±125549 J/mole]/RT
Bath gas:
Br2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 262 | 2.46E1 |
| 275 | 1.92E1 |
| 300 | 1.27E1 |
| 325 | 8.94E0 |
| 350 | 6.61E0 |
| 371 | 5.30E0 |