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Author(s):   Fettis, G.C.; Knox, J.H.; Trotman-Dickenson, A.F.
Title:   The reactions of bromine atoms with alkanes and methyl halides
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1960
Reference type:   Journal article
Squib:   1960FET/KNO4177

Reaction:   CH3Cl + Br··CH2Cl + HBr
Reaction order:   2
Reference reaction:   CH4 + Br··CH3 + HBr
Reference reaction order:   2
Temperature:   477 - 614 K
Rate expression:   3.6x10-1 e15881 [J/mole]/RT
Bath gas:   Br2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
477 1.97E1
500 1.64E1
525 1.37E1
550 1.16E1
575 9.98E0
600 8.69E0
614 8.08E0