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Home ©NIST, 2013 Accessibility information |
Title: Reaction Rate and Isomer-Specific Product Branching Ratios of C2H + C4H8: 1-Butene, cis-2-Butene, trans-2-Butene, and Isobutene at 79 K
Journal: J. Phys. Chem. A
Volume: 117
Page(s): 5093 - 5105
Year: 2013
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2013BOU/FOU5093-5105
Reaction:
(E)-2-C4H8 + ·C2H → CH3CH=CHC≡CH + ·CH3
Reaction order:
2
Reference reaction:
(E)-2-C4H8 + ·C2H → Products
Reference reaction order:
2
Temperature:
79.00
K
Pressure: 1.40E11 bar
Rate expression:
1.0
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Laval nozzle
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Mass spectrometry
Comments:
3-Penten-1-yne was the only product detected.
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