Author(s):   Dijkstra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal:   J. Chem. Soc. A
Page(s):
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER105

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |

Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1967DIJ/KER105	C₂H₄ + NF₂ → F₂NCH₂CH₂	351 - 428	6.61E-14	6.49E04		2
1967DIJ/KER105	1-C₄H₈ + NF₂ → C₂H₅CHCH₂NF₂	334 - 428	2.09E-14	5.69E04		2
1967DIJ/KER105	CH₃CH=CH₂ + NF₂ → CH₃CHCH₂NF₂	334 - 428	2.62E-14	5.73E04		2
1967DIJ/KER105	Isobutene + NF₂ → (CH₃)2CCH₂NF₂	314 - 428	1.05E-14	4.94E04		2
1967DIJ/KER105	Cyclopentene + NF₂ → HNF₂ + Cyclopentenyl	334 - 391	2.09E-15	5.60E04		2
1967DIJ/KER105	Cyclopentene + NF₂ → Cyclopentyl, 2-(difluoroamino)-	314 - 428	1.32E-15	4.61E04		2
1967DIJ/KER105	(CH₃)2C=CHCH₃ + NF₂ → CH₃CH(NF₂)C(CH₃)2	314 - 428	1.66E-15	4.22E04		2
1967DIJ/KER105	(CH₃)2C=C(CH₃)2 + NF₂ → (CH₃)2C(NF₂)C(CH₃)2	314 - 428	3.32E-16	3.48E04		2
1967DIJ/KER105	(Z)-2-C₄H₈ + NF₂ → CH₃CH(NF₂)CHCH₃	334 - 428	5.25E-15	4.98E04		2
1967DIJ/KER105	(E)-2-C₄H₈ + NF₂ → CH₃CH(NF₂)CHCH₃	334 - 428	5.25E-15	4.98E04		2
1967DIJ/KER105	CH₃CHCH₂NF₂ → CH₃CH=CH₂ + NF₂	334 - 428	6.02E20	5.65E04		1
Reference reaction: NF₂ + CH₃CHCH₂NF₂ → Propane, 1,2-(difluoroamino)-					2
1967DIJ/KER105	F₂NCH₂CH₂ → C₂H₄ + NF₂	373 - 428	1.90E23	5.73E04		1
Reference reaction: NF₂ + F₂NCH₂CH₂ → F₂NCH₂CH₂NF₂					2
1967DIJ/KER105	C₂H₅CHCH₂NF₂ → 1-C₄H₈ + NF₂	334 - 428	7.59E22	4.31E04		1
Reference reaction: NF₂ + C₂H₅CHCH₂NF₂ → CH₃CH₂CH(NF₂)CH₂NF₂					2
1967DIJ/KER105	CH₃CH(NF₂)CHCH₃ → (Z)-2-C₄H₈ + NF₂	334 - 428	2.41E24	5.69E04		1
Reference reaction: NF₂ + CH₃CH(NF₂)CHCH₃ → CH₃CH(NF₂)CH(NF₂)CH₃					2
1967DIJ/KER105	CH₃CH(NF₂)CHCH₃ → (E)-2-C₄H₈ + NF₂	334 - 428	2.41E24	5.69E04		1
Reference reaction: NF₂ + CH₃CH(NF₂)CHCH₃ → CH₃CH(NF₂)CH(NF₂)CH₃					2
1967DIJ/KER105	CH₃CH(NF₂)C(CH₃)2 → (CH₃)2C=CHCH₃ + NF₂	314 - 373	4.78E23	4.06E04		1
Reference reaction: NF₂ + CH₃CH(NF₂)C(CH₃)2 → CH₃CH(NF₂)C(NF₂)(CH₃)2					2
1967DIJ/KER105	(CH₃)2C(NF₂)C(CH₃)2 → (CH₃)2C=C(CH₃)2 + NF₂	314 - 373	3.01E22	3.48E04		1
Reference reaction: NF₂ + (CH₃)2C(NF₂)C(CH₃)2 → Butane, 2,3-(difluoroamino)-2,3-dimethyl-					2
1967DIJ/KER105	Cyclopentyl, 2-(difluoroamino)- → Cyclopentene + NF₂	334 - 391	6.02E21	4.10E04		1
Reference reaction: NF₂ + Cyclopentyl, 2-(difluoroamino)- → 1,2-Cyclopentanediamino, N,N,N',N'-tetrafluoro-					2

Search returned 18 records.