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Title: Absolute rate of recombination of CF2Cl. Radicals
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 65
Page(s):
Year: 1969
Reference type: Journal article
Squib: 1969MAJ/OLA2988
Reaction:
·CClF2 + ·CClF2 → CF2Cl-CF2Cl
Reaction order:
2
Temperature:
486 - 541
K
Pressure: 5.33E-2 - 0.11 bar
Rate expression:
3.22x10-11 [cm3/molecule s] e-1937 [J/mole]/RT
Bath gas:
Cyclohexane, undecafluoro-
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 486 | 1.99E-11 |
| 500 | 2.02E-11 |
| 525 | 2.07E-11 |
| 541 | 2.09E-11 |