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 Author(s):   Cvetanovic, R.J.
Title:   Evaluated chemical kinetic data for the reactions of atomic oxygen O(3P) with unsaturated hydrocarbons
Journal:   J. Phys. Chem. Ref. Data
Volume:   16
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987CVE261

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987CVE261   Benzene + O· → Products  298 - 600   2.52E-11       1.77E04   1.99E-14  2
  1987CVE261   C2H4 + O· → Products  200 - 500   1.06E-11       6652   7.25E-13  2
  1987CVE261   C2H2 + O· → Products  250 - 1300   2.66E-11       1.29E04   1.46E-13  2
  1987CVE261   C2H2 + O· → CO + ·CH2  300 - 2500   3.49E-12   1.50   7067      2
  1987CVE261   C2H2 + O· → H· + HCCO  1000 - 2500   7.14E-10       5.07E04      2
  1987CVE261   CH3CCH + O· → Products  290 - 1300   2.18E-11       8314   7.59E-13  2
  1987CVE261   CH2=CHCl + O· → Products  290 - 450   5.65E-12       5571   5.96E-13  2
  1987CVE261   CH2=CHF + O· → Products  290 - 450   8.97E-12       8564   2.83E-13  2
  1987CVE261   CH2=CCl2 + O· → Products  298   9.80E-13           9.80E-13  2
  1987CVE261   CH2=CF2 + O· → Products  290 - 450   6.97E-12       9312   1.63E-13  2
  1987CVE261   C2HCl3 + O· → Products  298   9.80E-14           9.80E-14  2
  1987CVE261   CF2=CCl2 + O· → Products  290 - 450   5.81E-12       5488   6.35E-13  2
  1987CVE261   C2F3Cl + O· → Products  290 - 450   3.82E-11       1.08E04   4.87E-13  2
  1987CVE261   alpha-pinene + O· → Products  290 - 450   3.16E-10       5903   2.91E-11  2
  1987CVE261   1,2-Dimethylbenzene + O· → Products  298 - 600   2.49E-11       1.15E04   2.43E-13  2
  1987CVE261   1,2,4-Trimethylbenzene + O· → Products  298 - 400   1.49E-11       6652   1.02E-12  2
  1987CVE261   t-Butylbenzene + O· → Products  298   6.64E-14           6.64E-14  2
  1987CVE261   Trifluoromethylbenzene + O· → Products  298   5.81E-15           5.81E-15  2
  1987CVE261   Ethylbenzene + O· → Products  298   9.96E-14           9.96E-14  2
  1987CVE261   1,4-Dimethylbenzene + O· → Products  298 - 600   2.61E-11       1.17E04   2.30E-13  2
  1987CVE261   1-C4H8 + O· → Products  290 - 450   1.34E-11       2910   4.15E-12  2
  1987CVE261   1,3-Butadiene + O· → Products  290 - 500   2.32E-11       333   2.03E-11  2
  1987CVE261   1-butyne + O· → CH3CH=CH2 + CO  298 - 1300   3.32E-11       6943   2.02E-12  2
  1987CVE261   CH2=CHCH2Cl + O· → Products  298   1.01E-12           1.01E-12  2
  1987CVE261   1,3-Dimethylbenzene + O· → Products  298 - 600   2.49E-11       1.01E04   4.15E-13  2
  1987CVE261   1,3,5-Trimethylbenzene + O· → Products  298 - 600   9.96E-12       3326   2.60E-12  2
  1987CVE261   Toluene + O· → Products  298 - 932   2.71E-11       1.43E04   8.43E-14  2
  1987CVE261   Chlorobenzene + O· → Products  298   4.98E-13           4.98E-13  2
  1987CVE261   1-C5H10 + O· → Products  290 - 450   1.59E-11       -108   1.66E-11  2
  1987CVE261   Cyclohexene + O· → Products  290 - 500   2.16E-11       249   1.95E-11  2
  1987CVE261   Pyridine + O· → Products  300 - 500   4.82E-12       1.05E04      2
  1987CVE261   CH3CH=CH2 + O· → Products  290 - 450   1.01E-11       2328   3.96E-12  2
  1987CVE261   Isobutene + O· → Products  290 - 450   1.59E-11       -108   1.66E-11  2
  1987CVE261   C2F4 + O· → Products  290 - 400   2.66E-12       2577   9.39E-13  2
  1987CVE261   CF3CF=CF2 → Products  297 - 398   1.30E-12       9728   2.55E-14  2
  1987CVE261   beta-pinene + O· → Products  290 - 450   2.49E-10       5488   2.72E-11  2
  1987CVE261   Cyclopentene + O· → Products  290 - 450   2.37E-11       333   2.08E-11  2
  1987CVE261   C2HF3 + O· → Products  290 - 450   1.01E-11       7899   4.18E-13  2
  1987CVE261   CH3C(CF3)=CH2 + O· → Products  200 - 450   9.61E-12       7832   4.07E-13  2
  1987CVE261   CH3CH2CF=CF2 + O· → Products  298   4.07E-12           4.07E-12  2
  1987CVE261   CH3CH=CF2 + O· → Products  298   1.83E-12           1.83E-12  2
  1987CVE261   1,3-Butadiyne + O· → Products  298 - 1300   7.47E-11       8231   2.70E-12  2
  1987CVE261   Fluorobenzene + O· → Products  298   1.33E-14           1.33E-14  2
  1987CVE261   CH2=C=CH2 + O· → Products  290 - 500   2.82E-11       7732   1.25E-12  2
  1987CVE261   H2C=C=O + O· → Products  230 - 449   2.99E-12       5654   3.05E-13  2
  1987CVE261   2-butyne + O· → CH3CH=CH2 + CO  290 - 360   9.96E-11       7483   4.86E-12  2
  1987CVE261   (CH3)2C=CHCH3 + O· → Products  290 - 400   2.82E-11       -1663   5.52E-11  2
  1987CVE261   1,2,3-Trimethylbenzene + O· → Products  298 - 400   1.66E-11       6652   1.13E-12  2
  1987CVE261   (CH3)2CHCH=CH2 + O· → Products  290 - 500   9.96E-12       2212   4.08E-12  2
  1987CVE261   (CH3)2C=C(CH3)2 + O· → Products  290 - 550   2.49E-11       -2494   6.82E-11  2
  1987CVE261   (Z)-2-C4H8 + O· → Products  290 - 500   1.10E-11       -1164   1.76E-11  2
  1987CVE261   1-Methylcyclohexene + O· → Products  290 - 450   2.32E-11       -3326   8.90E-11  2
  1987CVE261   1-C6H12 + O· → Products  298   4.65E-12           4.65E-12  2
  1987CVE261   1,3-Cyclohexadiene + O· → Products  290 - 450   2.32E-11       -3326   8.90E-11  2
  1987CVE261   CH2=CHBr + O· → Products  230 - 449   9.30E-12       6943   5.64E-13  2
  1987CVE261   (CH3)2C=C=O + O· → Products  230 - 449   5.98E-12       -4739   4.05E-11  2
  1987CVE261   (E)-2-C4H8 + O· → Products  290 - 450   2.16E-11       -83.14   2.23E-11  2
  1987CVE261   2-(Z)-C5H10 + O· → Products  298   1.66E-11           1.66E-11  2
  1987CVE261   CH2FCH2CH=CH2 + O· → Products  298   2.32E-12           2.32E-12  2
  1987CVE261   C2D4 + O· → Products  200 - 500   1.06E-11       6652   7.25E-13  2
  1987CVE261   CF2=CFCF=CF2 + O· → Products  298   3.65E-13           3.65E-13  2
  1987CVE261   Vinylacetylene + O· → Products  298 - 1300   4.98E-11       7566   2.35E-12  2
  1987CVE261   CH2=CHCH2F + O· → Products  298   8.30E-13           8.30E-13  2
  1987CVE261   C2D2 + O· → Products  298   1.43E-13           1.43E-13  2
  1987CVE261   Benzene-d6 + O· → Products  376 - 944   2.52E-11       1.77E04      2
  1987CVE261   C6H5CD3 + O· → Products  298 - 944   3.65E-11       1.50E04   8.70E-14  2
  1987CVE261   CH3CF=CH2 + O· → Products  298   1.99E-12           1.99E-12  2
  1987CVE261   CD3CD=CD2 + O· → Products  298   3.99E-12           3.99E-12  2
  1987CVE261   (Z)-CHF=CHF + O· → Products  290 - 450   1.19E-11       9728   2.35E-13  2
  1987CVE261   (E)-CHF=CHF + O· → Products  290 - 450   1.34E-11       8647   4.10E-13  2
  1987CVE261   d-Limonene + O· → Products  290 - 450   4.48E-10       3326   1.17E-10  2
  1987CVE261   CH3CH=C=O + O· → Products  230 - 449   4.82E-12       -2079   1.11E-11  2
  1987CVE261   O· + C2H5CH=C=O → Products  230 - 449   5.31E-12       -1829   1.11E-11  2
  1987CVE261   O· + CH2=CHCF3 → Products  298   4.15E-14           4.15E-14  2
  1987CVE261   O· + 1,2-Di(methyl-d3)benzene-d4 → Products  298 - 600   3.49E-11       1.29E04   1.92E-13  2
Search returned 75 records.