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Author(s):   Husain, D.; Lee, Y.H.
Title:   Measurement of absolute rate data for the reaction of atomic potassium, K(42S1/2), with CF3Cl, CF2Cl2, CFCl3, CF3Br and SF6 as a function of temperature by time-resolved atomic resonance λ = 404nm[K(52Pj) → K(42S1/2)]
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   83
Year:   1987
Reference type:   Journal article
Squib:   1987HUS/LEE2325

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987HUS/LEE2325   CF3Br + K → Products  728 - 857   3.90E-10       1.23E04      2
  1987HUS/LEE2325   CFCl3 + K → Products  701 - 810   1.00E-10              2
  1987HUS/LEE2325   CF2Cl2 + K → Products  739 - 834   2.09E-10       5504      2
  1987HUS/LEE2325   CF3Cl + K → Products  672 - 915   1.10E-10       1.38E04      2
  1987HUS/LEE2325   SF6 + KKF + SF5  691 - 810   8.40E-10       1.23E04      2

Search returned 5 records.