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Author(s):   Mazac, C.J.; Simons, J.W.
Title:   Relative rates of methylene radical reactions with silicon-hydrogen, silicon-deuterium, and carbon-hydrogen bonds in the methylsilane system
Journal:   J. Am. Chem. Soc.
Volume:   90
Page(s):   2484 - 2488
Year:   1968
Reference type:   Journal article
Squib:   1968MAZ/SIM2484-2488

Reaction:   CH3SiD3 + ·CH2 → CH3SiD2CH2D
Reaction order:   2
Reference reaction:   CH3SiD3 + ·CH2 → C2H5SiD3
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.27 - 0.53 bar
Rate expression:   7.69±3.1x10-1
Bath gas:   CH2N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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