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Title: Relative rates of methylene radical reactions with silicon-hydrogen, silicon-deuterium, and carbon-hydrogen bonds in the methylsilane system
Journal: J. Am. Chem. Soc.
Volume: 90
Page(s): 2484 - 2488
Year: 1968
Reference type: Journal article
Squib: 1968MAZ/SIM2484-2488
Reaction:
CH3SiD3 + ·CH2 → CH3SiD2CH2D
Reaction order:
2
Reference reaction:
CH3SiD3 + ·CH2 → C2H5SiD3
Reference reaction order:
2
Temperature:
298
K
Pressure: 0.27 - 0.53 bar
Rate expression:
7.69±3.1x10-1
Bath gas:
CH2N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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