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Author(s):   Rice, F.O.; Varnerin, R.E.
Title:   Activation energies of reactions of methyl radicals with organic molecules
Journal:   J. Am. Chem. Soc.
Volume:   77
Year:   1955
Reference type:   Journal article
Squib:   1955RIC/VAR221

Reaction:   iso-C4H10 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   CD3CDO + CD3CD4 + CD3CO
Reference reaction order:   2
Temperature:   773 - 833 K
Pressure:  0.27 bar
Rate expression:   2.13 e-7965 [J/mole]/RT
Bath gas:   CD3CDO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
773 6.17E-1
775 6.19E-1
800 6.43E-1
825 6.67E-1
833 6.74E-1