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Author(s):   Ahonkhai, S.I.; Lin, X-H.; Back, M.H.
Title:   Rate constants for abstraction of hydrogen from ethylene by methyl and ethyl radicals relative to abstraction from propane and isobutane
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   1 - 20
Year:   1989
Reference type:   Journal article
Squib:   1989AHO/LIN1-20

Reaction:   iso-C4H10 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   C2H4 + ·CH3CH4 + C2H3
Reference reaction order:   2
Temperature:   673 - 766 K
Pressure:  0.10 - 0.51 bar
Rate expression:   1.1x10-1 e38247 [±8398 J/mole]/RT
Uncertainty:   2.50999999
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
673 1.02E2
675 1.00E2
700 7.86E1
725 6.26E1
750 5.07E1
766 4.46E1