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Title: The Addition of Group VIa Atoms to Tetramethylethylene. An Addition Reaction with a Negative Activation Energy
Journal: J. Am. Chem. Soc.
Volume: 93
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971CON/VAN560
Reaction:
(E)-2-C4H8 + S → Thiirane, 2,3-dimethyl-, trans
Reaction order:
2
Temperature:
298
K
Pressure: 0.27 bar
Rate expression:
1.99x10-11 [±3.32x10-12 cm3/molecule s]
Bath gas:
CO2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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