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Author(s):   Connor, J.; Van Roodselaar, A.; Fair, R.W.; Strausz, O.P.
Title:   The Addition of Group VIa Atoms to Tetramethylethylene. An Addition Reaction with a Negative Activation Energy
Journal:   J. Am. Chem. Soc.
Volume:   93
Year:   1971
Reference type:   Journal article
Squib:   1971CON/VAN560

Reaction:   (E)-2-C4H8 + SThiirane, 2,3-dimethyl-, trans
Reaction order:   2
Temperature:   298 K
Pressure:  0.27 bar
Rate expression:   1.99x10-11 [±3.32x10-12 cm3/molecule s]
Bath gas:   CO2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

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