Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Strausz, O.P.; O'Callaghan, W.B.; Lown, E.M.; Gunning, H.E.
Title:   Reactions of Sulfur Atoms. XII. Arrhenius Parameters for the Addition to Olefins and Acetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971STR/OCA559

Reaction:   (E)-2-C4H8 + SThiirane, 2,3-dimethyl-, trans
Reaction order:   2
Reference reaction:   C2H4 + SThiirane
Reference reaction order:   2
Temperature:   298 - 450 K
Pressure:  0.27 bar
Rate expression:   6.5x10-1 e8398 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.93E1
300 1.88E1
325 1.45E1
350 1.16E1
375 9.61E0
400 8.12E0
425 7.00E0
450 6.13E0