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Author(s):   Strausz, O.P.; O'Callaghan, W.B.; Lown, E.M.; Gunning, H.E.
Title:   Reactions of Sulfur Atoms. XII. Arrhenius Parameters for the Addition to Olefins and Acetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Year:   1971
Reference type:   Journal article
Squib:   1971STR/OCA559

Reaction:   (E)-2-C4H8 + SThiirane, 2,3-dimethyl-, trans
Reaction order:   2
Reference reaction:   C2H4 + SThiirane
Reference reaction order:   2
Temperature:   298 - 450 K
Pressure:  0.27 bar
Rate expression:   6.5x10-1 e8398 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.93E1
300 1.88E1
325 1.45E1
350 1.16E1
375 9.61E0
400 8.12E0
425 7.00E0
450 6.13E0