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Author(s):   Falbe-Hansen, H.; Sorensen, S.; Jensen, N.R.; Pedersen, T.; Hjorth, J.
Title:   Atmospheric gas-phase reactions of dimethylsulphoxide and dimethylsulphone with ON and NO3 radicals, Cl atoms and ozone
Journal:   Atmos. Environ.
Volume:   34
Page(s):   1543 - 1551
Year:   2000
Reference type:   Journal article
Squib:   2000FAL/SOR1543-1551

Reaction:   (CH3)2SO + O3 → Products
Reaction order:   2
Temperature:   295 K
Pressure:  0.99 bar
Rate expression:   1.0x10-19 [cm3/molecule s]
Rate constant is an upper limit.
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The rate constant was determined by pseudo-first-order method

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