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Title: Atmospheric gas-phase reactions of dimethylsulphoxide and dimethylsulphone with ON and NO3 radicals, Cl atoms and ozone
Journal: Atmos. Environ.
Volume: 34
Page(s): 1543 - 1551
Year: 2000
Reference type: Journal article
Squib: 2000FAL/SOR1543-1551
Reaction:
(CH3)2SO + O3 → Products
Reaction order:
2
Temperature:
295
K
Pressure: 0.99 bar
Rate expression:
1.0x10-19 [cm3/molecule s]
Rate constant is an upper limit.
Category: Experiment
Data type:
Relative value normalized by a reference value
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Discharge
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
The rate constant was determined by pseudo-first-order method
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