Author(s):   Wallington, T.J.; Guschin, A.; Hurley, M.D.
Title:   Comment: A kinetic study of chlorine radical reactions with ketones by laser-photolysis technique by Olsson et al.
Journal:   Int. J. Chem. Kinet.
Volume:   30
Page(s):   309 - 310
Year:   1998
Reference type:   Journal article
Squib:   1998WAL/GUS309-310

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1998WAL/GUS309-310	Cyclohexanone + ·Cl → Products	295	0.49		2
Reference reaction: Cyclohexane + ·Cl → Cyclohexyl + HCl				2
1998WAL/GUS309-310	Cyclohexanone + ·Cl → Products	295	1.79E-10		2
1998WAL/GUS309-310	Cyclohexanone + ·Cl → Products	295	2.08		2
Reference reaction: C₂H₄ + ·Cl → Products				2
1998WAL/GUS309-310	Cyclopentanone + ·Cl → Products	295	0.36		2
Reference reaction: Cyclopentane + ·Cl → Cyclopentyl + HCl				2
1998WAL/GUS309-310	Cyclopentanone + ·Cl → Products	295	1.11E-10		2
1998WAL/GUS309-310	Cyclopentanone + ·Cl → Products	295	1.20		2
Reference reaction: C₂H₄ + ·Cl → Products				2

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