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Author(s):   Olkhov, R.V.; Li, Q.; Osborne, M.C.; Smith, I.W.M.
Title:   Branching Ratios for Competing Channels in the Reaction of HOCO Radicals with NO
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   4522 - 4528
Year:   2001
Reference type:   Journal article
Squib:   2001OLK/LI4522-4528

Reaction:   M + NO + ·Cl → M + NOCl
Reaction order:   3
Temperature:   298 K
Rate expression:   5.1x10-32 [±7.0x10-33 cm6/molecule2 s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption

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