Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Olkhov, R.V.; Li, Q.; Osborne, M.C.; Smith, I.W.M.
Title:   Branching Ratios for Competing Channels in the Reaction of HOCO Radicals with NO
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   4522 - 4528
Year:   2001
Reference type:   Journal article
Squib:   2001OLK/LI4522-4528

Reaction:   M + NO + ·Cl → M + NOCl
Reaction order:   3
Temperature:   298 K
Rate expression:   5.1x10-32 [±7.0x10-33 cm6/molecule2 s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption

View full bibliographic record.