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Author(s):   Dijkstra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER105

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1967DIJ/KER105   C2H4 + NF2 → F2NCH2CH2  351 - 428   6.61E-14       6.49E04      2
  1967DIJ/KER105   1-C4H8 + NF2 → C2H5CHCH2NF2  334 - 428   2.09E-14       5.69E04      2
  1967DIJ/KER105   CH3CH=CH2 + NF2 → CH3CHCH2NF2  334 - 428   2.62E-14       5.73E04      2
  1967DIJ/KER105   Isobutene + NF2 → (CH3)2CCH2NF2  314 - 428   1.05E-14       4.94E04      2
  1967DIJ/KER105   Cyclopentene + NF2HNF2 + Cyclopentenyl  334 - 391   2.09E-15       5.60E04      2
  1967DIJ/KER105   Cyclopentene + NF2 → Cyclopentyl, 2-(difluoroamino)-  314 - 428   1.32E-15       4.61E04      2
  1967DIJ/KER105   (CH3)2C=CHCH3 + NF2 → CH3CH(NF2)C(CH3)2  314 - 428   1.66E-15       4.22E04      2
  1967DIJ/KER105   (CH3)2C=C(CH3)2 + NF2 → (CH3)2C(NF2)C(CH3)2  314 - 428   3.32E-16       3.48E04      2
  1967DIJ/KER105   (Z)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  334 - 428   5.25E-15       4.98E04      2
  1967DIJ/KER105   (E)-2-C4H8 + NF2 → CH3CH(NF2)CHCH3  334 - 428   5.25E-15       4.98E04      2
  1967DIJ/KER105   CH3CHCH2NF2CH3CH=CH2 + NF2  334 - 428   6.02E20       5.65E04      1
  Reference reaction:  NF2 + CH3CHCH2NF2Propane, 1,2-(difluoroamino)- 2
  1967DIJ/KER105   F2NCH2CH2C2H4 + NF2  373 - 428   1.90E23       5.73E04      1
  Reference reaction:  NF2 + F2NCH2CH2 → F2NCH2CH2NF2 2
  1967DIJ/KER105   C2H5CHCH2NF21-C4H8 + NF2  334 - 428   7.59E22       4.31E04      1
  Reference reaction:  NF2 + C2H5CHCH2NF2CH3CH2CH(NF2)CH2NF2 2
  1967DIJ/KER105   CH3CH(NF2)CHCH3(Z)-2-C4H8 + NF2  334 - 428   2.41E24       5.69E04      1
  Reference reaction:  NF2 + CH3CH(NF2)CHCH3 → CH3CH(NF2)CH(NF2)CH3 2
  1967DIJ/KER105   CH3CH(NF2)CHCH3(E)-2-C4H8 + NF2  334 - 428   2.41E24       5.69E04      1
  Reference reaction:  NF2 + CH3CH(NF2)CHCH3 → CH3CH(NF2)CH(NF2)CH3 2
  1967DIJ/KER105   CH3CH(NF2)C(CH3)2 → (CH3)2C=CHCH3 + NF2  314 - 373   4.78E23       4.06E04      1
  Reference reaction:  NF2 + CH3CH(NF2)C(CH3)2 → CH3CH(NF2)C(NF2)(CH3)2 2
  1967DIJ/KER105   (CH3)2C(NF2)C(CH3)2 → (CH3)2C=C(CH3)2 + NF2  314 - 373   3.01E22       3.48E04      1
  Reference reaction:  NF2 + (CH3)2C(NF2)C(CH3)2 → Butane, 2,3-(difluoroamino)-2,3-dimethyl- 2
  1967DIJ/KER105   Cyclopentyl, 2-(difluoroamino)- → Cyclopentene + NF2  334 - 391   6.02E21       4.10E04      1
  Reference reaction:  NF2 + Cyclopentyl, 2-(difluoroamino)- → 1,2-Cyclopentanediamino, N,N,N',N'-tetrafluoro- 2

Search returned 18 records.