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Accessibility information
Author(s):   Failes, R.L.; Stimson, V.R.
Title:   Catalysis by hydrogen halides in the gas phase. Part VI. Butan-2-ol and hydrogen bromide
Journal:   J. Chem. Soc.
Page(s):   653 - 656
Year:   1962
Reference type:   Journal article
Squib:   1962FAI/STI653-656

Reaction:   sec-C4H9OH → Other Products + H2O
Reaction order:   1
Temperature:   660 - 783 K
Pressure:  0.37 - 0.59 bar
Rate expression:   5.79x1012 [s-1] e-146335 [J/mole]/RT
Bath gas:   HBr
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
660 1.52E1
675 2.75E1
700 6.97E1
725 1.66E2
750 3.73E2
775 7.94E2
783 1.00E3