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Author(s):   Jackson, W.M.; McNesby, J.R.; Darwent, B.deB.
Title:   Reaction of methyl-d3 radicals with isobutane-2-d, and propane
Journal:   J. Chem. Phys.
Volume:   37
Year:   1962
Reference type:   Journal article
Squib:   1962JAC/MCN1610

Reaction:   iso-C4H10 + CD3CHD3 + tert-C4H9
Reaction order:   2
Reference reaction:   (CD3)2CO + CD3 → Other Products + CD4
Reference reaction order:   2
Temperature:   571 - 729 K
Pressure:  6.67E-2 bar
Rate expression:   2.0x10-1 e14633 [J/mole]/RT
Bath gas:   (CD3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
571 4.36E0
575 4.27E0
600 3.76E0
625 3.34E0
650 3.00E0
675 2.71E0
700 2.47E0
725 2.27E0
729 2.24E0