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Author(s):   Jackson, W.M.; McNesby, J.R.; Darwent, B.deB.
Title:   Reaction of methyl-d3 radicals with isobutane-2-d, and propane
Journal:   J. Chem. Phys.
Volume:   37
Page(s):  
Year:   1962
Reference type:   Journal article
Squib:   1962JAC/MCN1610

Reaction:   iso-C4H10 + CD3CHD3 + tert-C4H9
Reaction order:   2
Reference reaction:   CD3 + (CH3)3CDCD4 + tert-C4H9
Reference reaction order:   2
Temperature:   571 - 729 K
Pressure:  6.67E-2 bar
Rate expression:   8.0x10-1 e6693 [J/mole]/RT
Bath gas:   (CD3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
571 3.28E0
575 3.24E0
600 3.06E0
625 2.90E0
650 2.76E0
675 2.64E0
700 2.53E0
725 2.43E0
729 2.41E0